Nd:YVO4 Crystal
Basic Properties:  
> Atomic density:

~1.37 กม 1020 atoms/cm2

> Crystal structure

Zircon Tetragonal,space group D­­4h­­­­­ ,a=b=7.12,c=6.29

> Density

 4.22g/cm3

> Mohs Hardness

Glass-like,~5

> Thermal expansion coefficients

aa=4.43กม10-6/K  ac=11.37กม10-6/K

> Thermal conductivity coefficients

?C:5.23W/m/k; ?C:5.10W/m/K;

Optical Properties(typically for 1.1 atm% Nd:YVO4,a-cut crystals)

Lasing Wavelengths

914nm,1064nm,1342nm

 

Positive uniaxial,no=na=nb,ne=nc

Crystal class

no=1.9573, ne=2.1652,@1064nm

  no=1.9721, ne=2.1858,@808nm
 

no=2.0210, ne=2.2560,@532nm

Sellmeier equation(for pure YVO4 crystals):
 

no2=3.77834+0.069736/(?2-0.04724)-0.0108133•?2

  ne2=4.59905+0.110534/(?2-0.04813)-0.0122676•?2
Thermal optical coefficient:

dna/dT=8.5กม10-6/K  dnc/dT=3.0กม10-6/K

Stimulated emission cross -section 25.0กม1019cm2,@1064nm
Fluorescent lifetime

90µs,(about 50µsfor 2 atm% Nd doped) @808n

Absorption coefficient

31.4cm-1@808nm

Absorption length 0.32mm@808nm
Intrinsic loss

less 0.1%cm-1@1064nm

Gain bandwidth

0.96nm(257GHz) @1064nm

Polarized laser emission p polarization;parallel to optic axis (c-axis)

Diode pumped optical to optical efficiency>60%


Absorption Curves of Different Doping Nd:YVO4
Nd:YVO4shows high absorption coefficient at pumping wavelengths.Therefore,a crystal short-in-length(e.g.1mm)is preferred,and more compact lasers can be constructed by Using Nd:YVO4 than using Nd:YAG.Furthermore,it has a wide and smoothly-varied bandwidth of absorption,so that it allows of less stringent requirements of diode laser selection And wavelength control as compared with Nd:YAG.Different doping levels Nd:YVO4 are shown showed as beside:


                  



Copyright by:Nanjing Saifei
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2002.6